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2. Deprotection Akin to protection, the deprotection proceeds through pentacoodinated intermediates.This is no different under acidic conditions. The reaction mechanism is unlike the S N 1 path in carbon chemistry as silyl cations are unstable. The driving force of fluoride-based deprotection is the formation of Si-F bond, which is about 30 kcal/mol stronger than Si-O bond.
In Brief Erectile dysfunction is one of the most common complications of diabetes and also one of the most underdiagnosed. Providers need to understand the pathophysiology of this condition in their diabetic patients and make an effort to diagnose and treat it. By doing.
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The pathophysiology of ED during aging and its underlying molecular mechanisms are largely unknown. We hypothesized that increased RhoA/Rhokinase signaling is a major factor in the pathogenesis of ageassociated ED and the mechanism involves increased penile smooth muscle contractility through inhibition of myosin light chain phosphatase.
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A growing interest in female sexuality, mediators and cellular mechanisms affecting. lead to dennervation of the female erectile tissues with sexual dysfunction following.
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The introduction of PDE5 inhibitors as safe and well-tolerated orally active drugs for the treatment of erectile dysfunction has. to further elucidate the mechanisms of action of this class.
To date, benign diseases of the male and female lower urinary and genital tract, such as erectile dysfunction. in order to further elucidate the mechanisms of action of this class of drugs.
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Interestingly, in this study, this association to incident coronary heart disease was seen specifically with antibiotic purchases, making the potential pathophysiologic mechanisms behind this.
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